Abstract
To explore the rheological properties and the modification mechanism of graphene/rubber composite-modified asphalt, a dynamic shear rheometer and low-temperature bending rheometer were used to study the high and low-temperature rheological properties of graphene/rubber composite-modified asphalt. Second, the microstructure and chemical structure of the asphalt were characterized by using Fourier transform infrared spectroscopy and optical microscopy, and the component model of asphalt was constructed with molecular dynamics simulation technology to explore the modification mechanism of graphene/rubber composite-modified asphalt. The results show that compared with rubber-modified asphalt, graphene/rubber composite-modified asphalt effectively improves the high-temperature deformation resistance and low-temperature crack resistance of asphalt, but the ability of graphene to improve the low-temperature performance of asphalt is limited at −24°C or even lower temperatures. The addition of graphene promotes the swelling development of rubber, improves the bonding stability between rubber and resin, and enhances the compatibility between rubber and asphalt systems. Graphene can weaken the aggregation behavior of rubber and asphaltene, and the distribution of rubber and asphaltene in asphalt is more uniform, further improving the overall stability of the asphalt system. Graphene promotes the adsorption of lightweight components by rubber, leading to a decrease in the diffusion coefficients of saturated and aromatic components in asphalt systems. This is also an important reason for the improved high-temperature performance of graphene/rubber-modified asphalt.