Abstract

To explore the rheological properties and the modification mechanism of graphene/rubber composite-modified asphalt, a dynamic shear rheometer and low-temperature bending rheometer were used to study the high and low-temperature rheological properties of graphene/rubber composite-modified asphalt. Second, the microstructure and chemical structure of the asphalt were characterized by using Fourier transform infrared spectroscopy and optical microscopy, and the component model of asphalt was constructed with molecular dynamics simulation technology to explore the modification mechanism of graphene/rubber composite-modified asphalt. The results show that compared with rubber-modified asphalt, graphene/rubber composite-modified asphalt effectively improves the high-temperature deformation resistance and low-temperature crack resistance of asphalt, but the ability of graphene to improve the low-temperature performance of asphalt is limited at −24°C or even lower temperatures. The addition of graphene promotes the swelling development of rubber, improves the bonding stability between rubber and resin, and enhances the compatibility between rubber and asphalt systems. Graphene can weaken the aggregation behavior of rubber and asphaltene, and the distribution of rubber and asphaltene in asphalt is more uniform, further improving the overall stability of the asphalt system. Graphene promotes the adsorption of lightweight components by rubber, leading to a decrease in the diffusion coefficients of saturated and aromatic components in asphalt systems. This is also an important reason for the improved high-temperature performance of graphene/rubber-modified asphalt.

References

1.
Cui
Y. N.
,
Guo
L. D.
, and
Chen
D. S.
, “
Composite Aging Mechanism of SBS Modified Asphalt
,”
Journal of Building Materials
23
, no. 
5
(May
2020
):
1183
1191
, https://doi.org/10.3969/j.issn.1007-9629.2020.05.026
2.
Xu
S.
,
Fan
Y.
,
Feng
Z. G.
,
Ke
Y. B.
,
Zhang
C.
, and
Huang
H.
, “
Comparison of Quantitative Determination for SBS Content in SBS Modified Asphalt
,”
Construction and Building Materials
282
(May
2021
): 122733, https://doi.org/10.1016/j.conbuildmat.2021.122733
3.
Du
Z. Y.
,
Jiang
C. S.
,
Yuan
J.
,
Xiao
F.
, and
Wang
J.
, “
Low Temperature Performance Characteristics of Polyethylene Modified Asphalts-A Review
,”
Construction and Building Materials
264
(December
2020
): 120704, https://doi.org/10.1016/j.conbuildmat.2020.120704
4.
Jitsangiam
P.
,
Nusit
K.
,
Phenrat
T.
,
Kumlai
S.
, and
Pra-ai
S.
, “
An Examination of Natural Rubber Modified Asphalt: Effects of Rubber Latex Contents Based on Macro- and Micro-observation Analyses
,”
Construction and Building Materials
289
(June
2021
): 123158, https://doi.org/10.1016/j.conbuildmat.2021.123158
5.
Ren
S. S.
,
Liu
X. Y.
,
Fan
W. Y.
,
Qian
C.
,
Nan
G.
, and
Erkens
S.
, “
Investigating the Effects of Waste Oil and Styrene Butadiene Rubber on Restoring and Improving the Viscoelastic, Compatibility, and Aging Properties of Aged Asphalt
,”
Construction and Building Materials
269
(February
2021
): 121338, https://doi.org/10.1016/j.conbuildmat.2020.121338
6.
Xiao
F. P.
,
Shen
J. N.
, and
Amirkhanian
S. N.
, “
Effects of Various Long-Term Aging Procedures on the Rheological Properties of Laboratory Prepared Rubberized Asphalt Binders
,”
Journal of Testing and Evaluation
37
, no. 
4
(July
2009
):
329
336
, https://doi.org/10.1520/JTE101706
7.
Shi
R. X.
and
Qiu
W.
, “
Test and Analysis of Influencing Factors on Rutting Resistance of Rubber Asphalt Mixture
,”
New Building Materials
46
, no. 
6
(June
2019
):
153
156
, https://doi.org/10.3969/j.issn.1001-702X.2019.06.038
8.
Wu
W. J.
,
Jiang
W.
,
Xiao
J. J.
,
Yuan
D.
,
Wang
T.
, and
Xing
C.
, “
Analysis of Thermal Susceptibility and Rheological Properties of Asphalt Binder Modified with Microwave Activated Crumb Rubber
,”
Journal of Cleaner Production
377
(December
2022
): 134488, https://doi.org/10.1016/j.jclepro.2022.134488
9.
Bao
D. X.
,
Cao
C. X.
,
Zhang
F. K.
,
Dong
H. M.
, and
Wang
P.
, “
Effect of Graphene on Antiaging Properties of Rubber Modified Asphalt
,”
Journal of Building Materials
23
, no. 
5
(December
2020
):
1113
1120
, https://doi.org/10.3969/j.issn.1007-9629.2020.05.017
10.
Li
B. Y.
, “
Rheological Properties of Graphene/Polyethylene Composite Modified Asphalt Binder
,”
Bulletin of the Chinese Ceramic Society
40
, no. 
7
(August
2021
):
2461
2468
.
11.
Liu
J. W.
,
Hao
P. W.
,
Jiang
W. T.
, and
Sun
B.
, “
Rheological Properties of SBS Modified Asphalt Incorporated Polyvinylpyrrolidone Stabilized Graphene Nanoplatelets
,”
Construction and Building Materials
298
(September
2021
): 123850, https://doi.org/10.1016/j.conbuildmat.2021.123850
12.
Yu
R.
,
Wang
Q.
,
Wang
W.
,
Xiao
Y.
,
Wang
Z. Y.
,
Zhou
X.
,
Zhang
X.
,
Zhu
X.
, and
Fang
C.
, “
Polyurethane/Graphene Oxide Nanocomposite and Its Modified Asphalt Binder: Preparation, Properties and Molecular Dynamics Simulation
,”
Materials & Design
209
(November
2021
): 109994, https://doi.org/10.1016/j.matdes.2021.109994
13.
Meng
Y. J.
,
Zhang
R. J.
, and
Liu
Z. R.
, “
Research on the Effect of Graphene on Pavement Performance of Rubber Powder Modified Asphalt Mixture
,”
Highway
66
, no. 
5
(May
2021
):
7
11
.
14.
Zhang
X.
,
Huang
G.
,
Zhou
C.
,
Yuan
X. Y.
, and
He
J. X.
, “
Research Status of Graphene Material in Fields of Asphalt Composites
,”
Journal of Central South University
50
, no. 
7
(August
2019
): 8, https://doi.org/10.11817/j.issn.1672-7207.2019.07.017
15.
Nazki
M. A.
,
Chopra
T.
, and
Chandrappa
A. K.
, “
Rheological Properties and Thermal Conductivity of Bitumen Binders Modified with Graphene
,”
Construction and Building Materials
238
(March
2020
): 117693, https://doi.org/10.1016/j.conbuildmat.2019.117693
16.
Yao
H.
,
Dai
Q. L.
,
You
Z. P.
,
Ye
M.
, and
Yap
Y. K.
, “
Rheological Properties, Low-Temperature Cracking Resistance, and Optical Performance of Exfoliated Graphite Nanoplatelets Modified Asphalt Binder
,”
Construction and Building Materials
113
(June
2016
):
988
996
, https://doi.org/10.1016/j.conbuildmat.2016.03.152
17.
Chen
Y. Z.
,
Wang
Q.
,
Li
Z. X.
, and
Ding
S. Q.
, “
Rhysiological Properties of Graphene Nanoplatelets/Rubber Crowd Composite Modified Asphalt
,”
Construction and Building Materials
261
(November
2020
): 120505, https://doi.org/10.1016/j.conbuildmat.2020.120505
18.
Li
Z.
,
Guo
T.
,
Chen
Y.
,
Dong
L.
,
Chen
Q.
,
Hao
M.
,
Zhao
X.
, and
Liu
J.
, “
Study on Rheological Properties of Graphene Oxide/Rubber Crowd Composite-Modified Asphalt
,”
Materials
15
, no. 
18
(September
2022
): 6185, https://doi.org/10.3390/ma15186185
19.
Gao
Y. L.
,
Xie
Y. T.
,
Liao
M. J.
,
Li
Y.
,
Zhu
J.
, and
Tian
W.
, “
Study on the Mechanism of the Effect of Graphene on the Rheological Properties of Rubber-Modified Asphalt Based on Size Effect
,”
Construction and Building Materials
364
(January
2023
): 129815, https://doi.org/10.1016/j.conbuildmat.2022.129815
20.
Hu
K.
,
Yu
C. H.
,
Chen
Y. J.
,
Li
W.
,
Wang
D. D.
, and
Zhang
W. G.
, “
Multiscale Mechanisms of Asphalt Performance Enhancement by Crumbed Waste Tirlecular Dynae Rubber: Insight from Momics Simulation
,”
Journal of Molecular Modeling
27
, no. 
6
(May
2021
): https://doi.org/10.1007/s00894-021-04786-1
21.
Yu
C.
,
Hu
K.
,
Yang
Q.
,
Wang
D.
,
Zhang
W.
,
Chen
G.
, and
Kapyelata
C.
, “
Analysis of the Storage Stability Property of Carbon Nanotube/Recycled Polyethylene-Modified Asphalt Using Molecular Dynamics Simulations
,”
Polymers
13
, no. 
10
(May
2021
): 1658, https://doi.org/10.3390/polym13101658
22.
Liu
J. Z.
,
Liu
Q.
,
Wang
S. Y.
,
Zhang
X. Y.
,
Xiao
C. Y.
, and
Yu
B.
, “
Molecular Dynamics Evaluation of Activation Mechanism of Rejuvenator in Reclaimed Asphalt Pavement (RAP) Binder
,”
Construction and Building Materials
298
(September
2021
): 123898, https://doi.org/10.1016/j.conbuildmat.2021.123898
23.
Yang
K.
,
Zhou
D. H.
,
Wu
Q.
,
Liang
R.
,
Shangguan
S.
,
Liao
Z.
, and
Wei
N.
, “
Molecular Dynamics Study on the Glass Forming Process of Asphalt
,”
Construction and Building Materials
214
(July
2019
):
430
440
, https://doi.org/10.1016/j.conbuildmat.2019.04.138
24.
Ding
Y. J.
,
Tang
B. M.
,
Zhang
Y. C.
,
Wei
J. M.
, and
Cao
X. J.
, “
Molecular Dynamics Simulation to Investigate the Influence of SBS on Molecular Agglomeration Behavior of Asphalt
,”
Journal of Materials in Civil Engineering
27
, no. 
8
(August
2015
): C4104004, https://doi.org/10.1061/(ASCE)MT.1943-5533.0000998
25.
Xu
G. J.
and
Wang
H.
, “
Molecular Dynamics Study of Interfacial Mechanical Behavior between Asphalt Binder and Mineral Aggregate
,”
Construction and Building Materials
121
(September
2016
):
246
254
, https://doi.org/10.1016/j.conbuildmat.2016.05.167
26.
Standard Test Methods of Bitumen and Bituminous Mixtures for Highway Engineering
, JTG E20-2011 (Beijing, China:
China Communications Press
, approved November 1,
2011
).
27.
Meng
Y. J.
,
Guo
H. Y.
,
Xu
R. G.
,
Zhang
R. J.
, and
Ma
C. X.
, “
Rheological and Microscopic Properties of Graphene Rubber Composite Modified Asphalt
,”
Journal of Building Materials
23
, no. 
5
(November
2020
):
1246
1251
, https://doi.org/10.3969/j.issn.1007-9629.2020.05.034
28.
Liu
H. Q.
,
Zeiada
W.
,
Al-Khateeb
G. G.
,
Shanableh
A.
, and
Samarai
M.
, “
Use of the Multiple Stress Creep Recovery (MSCR) Test to Characterize the Rutting Potential of Asphalt Binders: A Literature Review
,”
Construction and Building Materials
269
(February
2021
): 121320, https://doi.org/10.1016/j.conbuildmat.2020.121320
29.
Standard Test Method for Determining the Flexural Creep Stiffness of Asphalt Binder Using the Bending Beam Rheometer (BBR)
, ASTM D6648-08(2016) (West Conshohocken, PA:
ASTM International
, approved October 1,
2016
), https://doi.org/10.1520/D6648-08R16
30.
Xu
X.
,
Leng
Z.
,
Lan
J. T.
,
Wang
W.
,
Yu
J.
,
Bai
Y.
,
Sreeram
A.
, and
Hu
J.
, “
Sustainable Practice in Pavement Engineering through Value-Added Collective Recycling of Waste Plastic and Waste Tyre Rubber
,”
Engineering
7
, no. 
6
(June
2021
):
857
867
, https://doi.org/10.1016/j.eng.2020.08.020
31.
Nian
T. F.
,
Li
P.
,
Mao
Y.
,
Zhang
G. H.
, and
Liu
Y.
, “
Connections between Chemical Composition and Rheology of Aged Base Asphalt Binders during Repeated Freeze-Thaw Cycles
,”
Construction and Building Materials
159
(January
2018
):
338
350
, https://doi.org/10.1016/j.conbuildmat.2017.10.097
32.
Lamontagne
J.
,
Dumas
P.
,
Mouillet
V.
, and
Kister
J.
, “
Comparison by Fourier Transform Infrared (FTIR) Spectroscopy of Different Ageing Techniques: Application to Road Bitumens
,”
Fuel
80
, no. 
4
(March
2001
):
483
488
, https://doi.org/10.1016/S0016-2361(00)00121-6
33.
Mirwald
J.
,
Werkovits
S.
,
Camargo
I.
,
Maschauer
D.
,
Hofko
B.
, and
Grothe
H.
, “
Understanding Bitumen Ageing by Investigation of Its Polarity Fractions
,”
Construction and Building Materials
250
(July
2020
): 118809, https://doi.org/10.1016/j.conbuildmat.2020.118809
34.
Mirwald
J.
,
Nura
D.
, and
Hofko
B.
, “
Recommendations for Handling Bitumen Prior to FTIR Spectroscopy
,”
Materials and Structures
55
, no. 
2
(January
2022
): 26, https://doi.org/10.1617/s11527-022-01884-1
35.
Mirwald
J.
,
Niszl
C.
,
Eberhardsteiner
L.
, and
Hofko
B.
. “
Quantifying the Influence of Heating and Resting on the Bitumen Microstructure
,”
Construction and Building Materials
400
(October
2023
): 132710, https://doi.org/10.1016/j.conbuildmat.2023.132710
36.
Guo
H. Y.
, “
Study on Performance of Graphene Rubber Composite Modified Asphalt and Asphalt Mixture
” (master’s thesis,
Guangxi University
,
2019
).
37.
Yu
J.
,
Zhao
Q.
,
Ye
F.
, and
Song
Q. Q.
, “
Low Temperature Rheological Performance Analysis of Rubber Modified Asphalt under Heat Aging Process
,”
Journal of Southwest Jiaotong University
56
, no. 
1
(January
2021
):
108
115
, https://doi.org/10.3969/j.issn.0258-2724.20180987
38.
He
J. X.
,
Hu
W.
,
Xiao
R.
,
Wang
Y.
,
Polaczyk
P.
, and
Huang
B.
, “
A Review on Graphene/GNPs/GO Modified Asphalt
,”
Construction and Building Materials
330
(May
2022
): 127222, https://doi.org/10.1016/j.conbuildmat.2022.127222
39.
Nie
F. H.
,
Jian
W.
, and
Lau
D.
, “
An Atomistic Study on the Thermomechanical Properties of Graphene and Functionalized Graphene Sheets Modified Asphalt
,”
Carbon
182
(September
2021
):
615
627
, https://doi.org/10.1016/j.carbon.2021.06.055
40.
Li
D. D.
and
Greenfield
M. L.
, “
Chemical Compositions of Improved Model Asphalt Systems for Molecular Simulations
,”
Fuel
115
(January
2014
):
347
356
, https://doi.org/10.1016/j.fuel.2013.07.012
41.
Zhang
L. Q.
and
Greenfield
M. L.
, “
Analyzing Properties of Model Asphalts Using Molecular Simulation
,”
Energy & Fuels
21
, no. 
3
(May
2007
):
1712
1716
, https://doi.org/10.1021/ef060658j
42.
Zhou
X. X.
,
Zhang
X.
,
Xu
S.
,
Wu
S. P.
,
Liu
Q. T.
, and
Fan
Z. P.
, “
Evaluation of Thermo-mechanical Properties of Graphene/Carbon-Nanotubes Modified Asphalt with Molecular Simulation
,”
Molecular Simulation
43
, no. 
4
(January
2017
):
312
319
, https://doi.org/10.1080/08927022.2016.1274985
43.
Jia
X. F.
, “
Study on Performance of Crumb Rubber/SBS Composite Modified Asphalt and Mixture
” (master’s thesis,
Lanzhou Jiaotong University
,
2020
).
44.
Xu
G. J.
and
Wang
H.
, “
Study of Cohesion and Adhesion Properties of Asphalt Concrete with Molecular Dynamics Simulation
,”
Computational Materials Science
112
, Part A (February
2016
):
161
169
, https://doi.org/10.1016/j.commatsci.2015.10.024
45.
He
L.
,
Li
G. N.
,
Zheng
Y. F.
,
Alessio
A.
,
Valentin
J.
, and
Kowalski
K. J.
, “
Progress and Prospects of Molecular Dynamics Research on Asphalt Systems
,”
Materials Reports
34
, no. 
19
(November
2020
):
19083
19093
, https://doi.org/10.11896/cldb.19070106
46.
Guo
F. C.
,
Pei
J. Z.
,
Huang
G. J.
,
Zhang
J.
,
Cannone Falchetto
A.
, and
Korkiala-Tanttu
L.
, “
Investigation of the Adhesion and Debonding Behaviors of Rubber Asphalt and Aggregates Using Molecular Dynamics Simulation
,”
Construction and Building Materials
371
(March
2023
): 130781, https://doi.org/10.1016/j.conbuildmat.2023.130781
47.
Chu
L.
,
Luo
L.
, and
Fwa
T. F.
, “
Effects of Aggregate Mineral Surface Anisotropy on Asphalt-Aggregate Interfacial Bonding Using Molecular Dynamics (MD) Simulation
,”
Construction and Building Materials
225
(November
2019
):
1
12
, https://doi.org/10.1016/j.conbuildmat.2019.07.178
48.
Kang
X.
,
Jiang
M. Y.
,
Ma
X. Y.
,
Liu
X. M.
, and
Yang
S.
, “
Study on Interface Interaction between Graphene Oxide Modified Asphalt and Surface Anisotropic Aggregate
,”
Journal of Hunan University
48
, no. 
9
(September
2021
):
70
78
, https://doi.org/10.16339/j.cnki.hdxbzkb.2021.09.008
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