Abstract

Currently, ASTM cooling curve analysis standards ASTM D6200 “Standard Test Method for Determination of Cooling Characteristics of Quench Oils by Cooling Curve Analysis,” D6482 “Standard Test Method for Determination of Cooling Characteristics of Aqueous Polymer Quenchants by Cooling Curve Analysis with Agitation,” and D6549 “Standard Test Method for Determination of Cooling Characteristics of Quenching by Cooling Curve Analysis with Agitation (Drayton Unit),” describe the experimental methodology for cooling curve data acquisition but leave the analysis of the resulting time-temperature cooling data up to the user. Therefore, it is of interest to provide an overview of the various methodologies that may be used by the user of these standards for data analyses and reporting. This is important in order to assess the impact of quench severity on resulting metallurgical properties of various steel alloys. The objective of this paper is to provide a general overview of approaches used to quantify not only the time-temperature behavior, but also a general quantitative assessment of relative quench severity exhibited by the various quenching media being analyzed. Methods for characterizing and interpreting cooling time-temperature curves are reviewed and the reasons for their utilization are discussed.

References

1.
Lakin
,
J. J.
, “
Testing of Quenching Media
,”
Heat Treat. Met.
 0305-4829, Vol.
3
,
1979
, pp.
59
62
.
2.
King
,
L. V.
, “
XII—On the Convection of Heat from Small Cylinders in a Stream of Fluid: Determination of the Convection Constants of Small Platinum Wires with Applications to Hot-Wire Anemometry
,”
Philos. Trans. R. Soc. London, Ser. A
 0962-8428 https://doi.org/10.1098/rsta.1914.0023, Vol.
214
,
1914
, pp.
373
433
.
3.
Russell
,
A. S.
,
Philos. Mag.
 0031-8086, Vol.
90
,
1910
, pp.
591
610
.
4.
Fourier
,
J.
, “
Mémoire d’Analyse sur le Mouvement de la Chaleur dans les Fluides
,”
Mem. Acad. Sci. Inst. Fr.
 0368-9263, Vol.
12
,
1820
, pp.
507
530
.
5.
Paschkis
,
V.
, “
Quenching of Steel Balls and Rings
,”
Trans. Am. Soc. Met.
 0096-7416, Vol.
37
,
1946
, pp.
216
244
.
6.
French
,
H. J.
, and
Klopsch
,
O. Z.
, “
Initial Temperature and Mass Effects in Quenching
,”
Trans. Am. Soc. Steel Treat.
, Vol.
9
,
1926
, pp.
33
74
.
7.
Pilling
,
N. B.
, “
The Quenching Behavior of Liquids
,”
Phys. Rev.
 0031-899X, Vol.
14
, No.
3
,
1919
, pp.
222
227
.
8.
Greenwood
,
J. A.
, and
Harris
,
J.
, “
Electrical Conduction in Solids. III. The Contact of Iron Surfaces
,”
Philos. Trans. R. Soc. London, Ser. A
 0962-8428, Vol.
257
, No.
1288
,
1960
, pp.
83
97
.
9.
Rasskazovskii
,
A. S.
, “
Cooling Ability of Quenching Liquids
,”
Metal Science and Heat Treatment
, Vol.
27
, No.
1
,
1985
, pp.
80
82
.
10.
Webster
,
G. M.
, and
Totten
,
G. E.
, “
Cooling Curve Analysis—Data Acquisition
,” in
Heat Treating: Proceedings of the 16 th Conference
,
J. L.
Dossett
and
R. E.
Luetje
, Eds.,
ASM International
,
Materials Park, OH
,
1996
, pp.
427
434
.
11.
Totten
,
G. E.
,
Bates
,
C. E.
, and
Clinton
,
N. A.
, “
Cooling Curve Analysis
,” in
Handbook of Quenchants and Quenching Technology
,
ASM International
,
Materials Park, OH, USA
,
1993
, chap. 3, pp.
69
128
.
12.
Bernardin
,
J. D.
, and
Mudawar
,
I.
, “
Validation of the Quench Factor Technique in Predicting Hardness in Heat Treatable Aluminum Alloys
,”
Int. J. Heat Mass Transfer
 0017-9310, Vol.
38
, No.
5
,
1995
, pp.
869
873
.
13.
Liscic
,
B.
,
Tensi
,
H. M.
, and
Totten
,
G. E.
, “
Non-Lubricating Process Fluids: Steel Quenching Technology
,” in
ASTM Fuels and Lubricants Handbook—Technology, Properties, Performance and Testing
,
G. E.
Totten
,
S. R.
Westbrook
, and
R. J.
Shah
, Eds.,
ASTM International
,
West Conshohocken, PA
,
2003
, chap. 22, pp.
587
634
.
14.
Varlamov
,
Yu. D.
,
Meshcheryakov
,
Yu. P.
,
Lezhnin
,
S. I.
,
Predtechenskii
,
M. R.
, and
Ul’yankin
,
S. N.
, “
Evolution of a Vapor Cavity During Explosive Boiling on a Film Microheater: Experiment and Numerical Simulation
,”
J. Appl. Mech. Tech. Phys.
 0021-8944, Vol.
48
, No.
4
,
2007
, pp.
534
541
.
15.
Kobasko
,
N. I.
,
Moskalenko
,
A. A.
,
Totten
,
G. E.
, and
Webster
,
G. M.
, “
Experimental Determination of the First and Second Critical Heat Flux Densities and Quench Process Characterization
,”
J. Mater. Eng. Perform.
 1059-9495 https://doi.org/10.1007/s11665-997-0037-9, Vol.
6
, No.
1
,
1997
, pp.
93
101
.
16.
Liscic
,
B.
, “
Critical Heat-Flux Densities, Quenching Intensity and Heat Extraction Dynamics During Quenching in Vaporizable Fluids
,”
Proceedings of the 22nd Heat Treating Society Conference and the 2nd International Surface Engineering Congress
, 15–17 September
2003
, Indianapolis, IN,
ASM International
,
Materials Park, OH
, pp.
161
168
.
17.
Kobasko
,
N. I.
,
Moskalenko
,
A. A.
,
Totten
,
G. E.
, and
Webster
,
G. M.
, “
Experimental Determination of the First and Second Critical Heat Flux Densities and Quench Process Characterization
,”
J. Mater. Eng. Perform.
 1059-9495 https://doi.org/10.1007/s11665-997-0037-9, Vol.
6
, No.
1
,
1997
, pp.
93
101
.
18.
Prabhu
,
K. N.
, and
Fernandes
,
P.
, “
Effect of Surface Roughness on Metal/Quenchant Interfacial Heat Transfer and Evolution of Microstructure
,”
Mater. Des.
 0264-1275, Vol.
28
,
2007
, pp.
544
550
.
19.
Tensi
,
H. M.
, “
Wetting Kinematics
,” in the
Handbook of the Theory and Technology of Quenching
,
B.
Liscic
,
H. M.
Tensi
, and
W.
Luty
, Eds.,
Springer-Verlag
,
Berlin, Germany
,
1991
, pp.
93
116
;
Leidenfrost
,
J. G.
, “
On the Fixation of Water in Diverse Fire
,”
Int. J. Heat Mass Transfer
 0017-9310 https://doi.org/10.1016/0017-9310(66)90111-6, Vol.
9
,
1966
, pp.
1153
1166
(English translation of original 1756 paper written in latin entitled: “A Tract About Some Qualities of Common Water”).
20.
Ladish
,
R.
, “
Untersuchung der minimalen Filmsiedietemperaturen auf keramischen und metallischen Leitern
,” Report of “Kernforschungstelle Karlsruhe,” KfK-2970,
1980
, 160 pp.
21.
Tensi
,
H. M.
, and
Totten
,
G. E.
, “
Development of the Understanding of the Influence of Wetting Behavior on Quenching and the Merits in these Developments of Prof. Imao Tamura
,” in
Conf. Proceed. Second International Conference on Quenching and Control of Distortion
,
G. E.
Totten
,
K.
Funatani
,
M. A. H.
Howes
, and
S.
Sjostrom
, Eds., 4–7 November
1996
,
ASM International
,
Materials Park, OH
, pp.
17
27
.
22.
Künzel
,
T.
, “
Einfluss der Wiederbenetzung auf die allotrope Modifkatsionsänderung tauchgekühlter Metallkörper
,” Dissertation,
Faculty for Mechanical Engineering of the Technical University of Munich
,
1986
, 138 pp.
23.
Stitzelberger-Jakob
,
P.
, “
Härtervorherbestimmung mit Hilfe des Benetzungsablaufes beim Tauschkühlen von Stählen
,” Dissertation,
Faculty for Mechanical Engineering of the Technical University of Munich
,
1991
, 160 pp.
24.
Hilder
,
N. A.
, “
Behaviour of Polymer Quenchants
,”
Heat Treat. Met.
 0305-4829, Vol.
14
, No.
2
,
1987
, pp.
31
46
.
25.
Hilder
,
N. A.
, “
Pump Agitation System for Assessing the Cooling Characteristics of Quenchants
,”
Heat Treat. Met.
 0305-4829, Vol.
12
, No.
3
,
1985
, pp.
63
68
.
26.
Mason
,
K. J.
, and
Capewell
,
I.
, “
Effect of Agitation on the Quenching Characteristics of Oil and Polymer Quenchants
,”
Heat Treat. Met.
 0305-4829, Vol.
13
, No.
4
,
1986
, pp. 99.
27.
Tensi
,
H. M.
, and
Steffen
,
E.
, “
Measuring of the Quenching Effect of Liquid Hardening Agents on the Basis of Synthetics
,”
Steel Res.
 0177-4832, Vol.
56
,
1985
, pp.
489
496
.
28.
Pilling
,
N. B.
, and
Lynch
,
T. D.
, “
Cooling Properties of Technical Quenching Liquids
,”
Trans. Am. Inst. Min., Metall. Pet. Eng.
 0096-4778, Vol.
62
,
1920
, pp.
665
688
.
29.
Grossman
,
M. A.
, and
Asimow
,
M.
, “
Hardenability and Quenching
,”
Iron Age
 0021-1508, Vol.
145
, No.
17
,
1940
, pp.
25
29
.
30.
Grossman
,
M. A.
, and
Asimov
,
M.
, “
Hardenability and Quenching
,”
Iron Age
 0021-1508, Vol.
145
, No.
18
,
1940
, pp.
39
47
.
31.
Reddy
,
A. V.
,
Akers
,
D. A.
,
Chuzoy
,
L.
,
Pershing
,
M. A.
, and
Woldow
,
R. A.
, “
A Simple Method Evaluates Quenches
,”
Heat Treating Progress
, Vol.
1
,
2001
, pp.
40
42
.
32.
Monroe
,
R. W.
, and
Bates
,
C. E.
, “
Evaluating Quenchants and Facilities for Hardening Steel
,”
J. Heat Treating
, Vol.
3
, No.
2
,
1983
, pp.
83
99
.
33.
Dakins
,
M. E.
,
Bates
,
C. E.
, and
Totten
,
G. E.
, “
Estimating Quench Severity with Cooling Curves
,”
Heat Treating
, Vol.
24
, No
4
,
1992
, pp.
24
26
.
34.
Tamura
,
I.
,
Shimizu
,
N.
, and
Okada
,
T.
, “
A Method to Judge the Quench-Hardening of Steel from Cooling Curves of Quenching Oils
,”
J. Heat Treating
, Vol.
3
, No.
4
,
1984
, pp.
335
343
.
35.
Bodin
,
J.
, and
Segerberg
,
S.
, “
Measurement and Evaluation of the Quenching Power of Quenching Media for Hardening
,” in
Proceed. of the First International Conference on Quenching and Control of Distortion
, Chicago, IL 22–25 September
1992
,
G. E.
Totten
, Ed.;
ASM International
,
Materials Park, OH
, pp.
1
11
.
36.
Tokihiro
,
Y.
, and
Tamura
,
I.
, “
Unification on Cooling Curves of Quenched Bars at Center
,”
Tetsu to Hagane
 0021-1575, Vol.
60
, No.
6
,
1974
, pp.
661
670
.
37.
French
,
H. J.
, “
A Study of the Quenching of Steels
,”
Trans. of the ASST
, Vol.
17
,
1930
, May, pp.
646
727
.
38.
Tokihiro
,
Y.
, and
Tamura
,
I.
, “
Applications of Master Cooling Curve
,”
Tetsu to Hagane
 0021-1575, Vol.
60
, No.
9
,
1974
, pp.
1337
1343
.
39.
Tokihiro
,
Y.
, and
Tamura
,
I.
,“
Estimation of Jominy Hardenability Curve by Master Cooling Curve
,”
Tetsu to Hagane
 0021-1575, Vol.
60
, No.
12
,
1974
, pp.
1639
1645
.
40.
Tokihiro
,
Y.
, and
Tamura
,
I.
, “
Method to Derive Cooling Curve of Specimen During Quenching
,”
Tetsu to Hagane
 0021-1575, Vol.
60
, No.
6
,
1974
, pp.
671
681
.
41.
Kobasko
,
N. I.
, and
Kostaniuk
,
D. M.
, “
Evaluation of Capacity of Quenchants on Basis using Inner Characteristic of the Boiling Process
,”
Material Science and Heat Treating (MiTOM)
, Vol.
10
,
1973
, pp.
21
27
.
42.
Wang
,
R. S.
,
Wang
,
Y.
, and
Su
,
L. P.
, “
Predicting the Quenching Effect on Steel Bars from the Measured Cooling Curves of Silver Bar Probes
,”
Transactions of Metal Heat Treatment (China)
, Vol.
8
, No.
1
,
1987
, pp.
30
39
.
43.
Wünning
,
J.
, and
Liedtke
,
D.
, “
Versuche zum Ermitteln der Wärmestromdichte beim Abschrecken con Stahl in flüssigen Anschreckmittln nach der QTA-Methode
,”
Härterei-Technische Mitteilungen
, Vol.
38
, No.
4
,
1983
, pp.
149
155
.
44.
Tensi
,
H. M.
,
Stich
,
A.
, and
Totten
,
G. E.
, “
Quenching and Quenching Technology
,” in
Handbook of Steel Heat Treatment
,
G. E.
Totten
and
M. A. H.
Howes
, Eds.,
Marcel Dekker
,
New York, NY USA
,
1997
, chap. 4, pp.
157
249
.
45.
Wünning
,
J.
, “
Berechnung und Steurung des Temperatur-verlaufs beim Abschrecken von Stahl in Wasser und Öl
,”
Härterei-Technische Mitteilungen
, Vol.
36
, No.
5
,
1981
, pp.
231
241
.
46.
Liscic
,
B.
, “
The QTA Method
,” in
Theory and Technology of Quenching—A Handbook
,
Springer-Verlag
,
Berlin, Germany
, chap. 11.2.1, pp.
409
419
.
47.
Thelning
,
K.-E.
, “
Correlation of the Measured Quenching Intensity with Hardness Distribution in Quenched Parts. IFHT Task 4
,”
Proceedings of the 5th Congress on Heat Treatment of Materials
, 20–24 October
1986
,
Scientific Society of Mechanical Engineers (GTE) Budapest
,
Hungary
, Vol.
3
, pp.
1737
1759
(Internet: http://www.gte.mtesz.hu/).
48.
Goryushin
,
V. V.
,
Arifmetchikov
,
V. F.
,
Tsvetkov
,
A. K.
, and
Sinetskii
,
S. N.
, “
Quenching Medium PK-2
,”
Metal Science and Heat Treatment
, Vol.
10
,
1986
, pp.
9
13
49.
Ksenofontov
,
A. G.
, and
Shevchenko
,
Yu. S.
, “
Criteria for Evaluating the Cooling capacity of quenching media
,”
Metal Science and Heat Treatment
, Vol.
40
, No.
9–10
,
1998
, pp.
408
411
[
Metallovedenie i Termicheskaya Obrabotka
, Vol.
40
, No.
9–10
,
1998
, pp.
408
411
].
50.
Khavskii
,
N. N.
,
Zhelokhovtseva
,
R. R.
, and
Logachev
,
A. I.
, “
Optimum Cooling During Steel Hardening
,”
Metal Science and Heat Treatment
, Vol.
25
, No.
1
,
1983
, pp.
23
26
[
Metallovedenie i Termicheskaya Obrabotka
, Vol.
25
, No.
1
,
1983
, pp.
23
26
].
51.
Deck
,
M.
, and
Damay
,
P.
, “
Castrol Index—A Method of Classifying Quenching Oils
,” Report presented at the French Heat Treating Association (A. T. T. T.), Lemans, France, September,
1990
.
52.
Bodin
,
J.
, and
Segerberg
,
S.
, “
Measurement and Evaluation of the Power of Quenching Media for Hardening
,”
Heat Treat. Met.
 0305-4829, Vol.
20
, No.
1
,
1993
, pp.
15
23
.
53.
Bodin
,
J.
, and
Segerberg
,
S.
, “
Measurement and Evaluation of the Power of Quenching Media for Hardening
,”
Proceed. of the First Int. Conf. on Quenching and Control of Distortion
,
G. E.
Totten
, Ed., 22–25 September
1992
,
ASM International
,
Materials Park, OH, USA
, pp.
1
12
.
54.
Segerberg
,
S. O.
, “
Classification of Quench Oils: A Method of Comparison
,”
Heat Treating
, Vol.
20
, No.
12
,
1988
, pp.
30
33
.
55.
Hilder
,
N. A.
, “
Quenchant Testing
,”
Heat Treat. Met.
 0305-4829, Vol.
17
, No.
3
,
1990
, pp. 67.
56.
Chen
,
C.
, and
Zhou
J.
, “
Discussions on Segerberg Formula Concerning the Hardening Power of Quenchants
,”
J. Shanghai Jiaotong Univ.
 0253-9942, Vol.
36
, No.
1
,
2002
, pp.
78
82
.
57.
Rose
,
A.
, “
Das Abkühlungsvermögen von Stahl—Absscreckmilleln
,”
Archiv. für das Eisenhüttenwesen
, Vol.
13
, No.
8
,
1940
, pp.
345
354
.
58.
Canale
,
L. C. F.
,
Kobasko
,
N. I.
, and
Totten
,
G. E.
, “
Intensive Quenching: Part 1—What Is It?
,”
International Heat Treatment and Surface Engineering
, Vol.
1
, No.
1
,
2007
, pp.
30
33
.
59.
Canale
,
L. C. F.
,
Kobasko
,
N. I.
, and
Totten
,
G. E.
, “
Intensive Quenching: Part 2—Formation of Optimal Surface Compressive Stresses
,”
International Heat Treatment and Surface Engineering
, Vol.
1
, No.
2
,
2007
, pp.
60
63
.
60.
Kobasko
,
N. I.
,
Totten
,
G. E.
,
Webster
,
G. M.
, and
Bates
,
C. E.
, “
Comparison of Cooling Capacity of Poly(Alkylene Glycol) Quenchants with Water and Oil
,” in
18th Heat Treating Society Conference Proceedings
,
H.
Walton
and
R.
Wallis
, Eds.,
ASM International
,
Materials Park, OH
,
1998
, pp.
559
567
.
61.
Fernandes
,
P.
, and
Prabhu
,
K. N.
, “
Comparative Study of Heat Transfer and Wetting Behaviour of Conventional and Bioquenchants for Industrial Heat Treatment
,”
Int. J. Heat Mass Transfer
 0017-9310 https://doi.org/10.1016/j.ijheatmasstransfer.2007.05.018, Vol.
51
,
2008
, pp.
526
538
.
62.
Beck
,
J. V.
, “
Surface Heat Flux Determination Using an Integral Method
,”
Nucl. Eng. Des.
 0029-5493 https://doi.org/10.1016/0029-5493(68)90058-7, Vol.
7
,
1968
, pp.
170
178
.
63.
Penha
,
R. N.
,
Canale
,
L. C. F.
,
Totten
,
G. E.
, and
Sarmiento
,
G. S.
, “
Simulation of Heat Transfer Properties and Residual Stress Analyses of Cooling Curves Obtained from Quenching Studies
J. ASTM Int.
 1546-962X, Vol.
3
, No.
5
,
2006
, Paper ID No. 13614.
64.
Hernandez-Morales
,
B.
,
Brimacombe
,
J. K.
, and
Hawbolt
,
E. B.
, “
Application of Inverse Techniques to Determine Heat-Transfer Coefficients in Heat-Treating Operations
,”
J. Mater. Eng. Perform.
 1059-9495, Vol.
1
, No.
6
,
1992
, pp.
763
771
.
65.
Inoue
,
A.
,
Takahashi
,
K.
,
Takahashi
,
M.
, and
Matsuzaki
,
M.
, “
Transient Film Boiling Under Transient Conditions Related to Vapor Explosion (Effects of Transient Flow and Fragmentation Under a Shock Pressure)
,”
Nucl. Eng. Des.
 0029-5493, Vol.
155
, No.
1–2
,
1995
, pp.
55
66
.
66.
Moskalenko
,
A. A.
,
Kobasko
,
N. I.
,
Tolmachova
,
O. V.
,
Totten
,
G. E.
, and
Webster
,
G. M.
, “
Quenchants Characterization by Acoustical Noise Analysis Cooling Properties of Aqueous Poly(Alkylene Glycol) Polymer Quenchants
,”
Conf. Proceed. 2nd International Conference on Quenching and Control of Distortion
,
G. E.
Totten
,
K.
Funatani
,
M. A. H.
Howes
, and
S.
Sjostrom
, Eds.,
ASM International
,
Materials OH
,
1996
, pp.
117
122
.
67.
Kobasko
,
N.
, “
Some New Approaches in the Field of Quenching Fundamentals
,” in
Proceed. of the 24th ASM Heat Treating Society Conference
, 17–19 September 2007, COBO Center, Detroit, NI, USA,
D.
Herring
and
G.
Pfaffmann
, Eds.,
2007
,
ASM International
,
Materials Park, OH
, pp.
134
140
.
68.
Kruzhilin
,
G. N.
, “
Free-Convection Transfer of Heat from a Horizontal Plate and Boiling Liquid
,”
Dokl. Akad. Nauk SSSR
 0002-3264, Vol.
58
, No.
8
,
1947
, pp.
1657
1660
.
69.
Kobasko
,
N.
,
Krukovskyi
,
P.
, and
Yurchenko
,
D.
, “
Initial and Critical Heat Flux Densities Evaluated on the Basis of CFD Modeling and Experiments during Intensive Quenching
,”
Proceed. of the 5th OASME/WSEAS Int. Conference on Heat Transfer, Thermal Engineering and Environment
,
Athens, Greece
, 25–27 August
2007
, pp.
295
298
.
70.
Kobasko
,
N. I.
, and
Guseynov
,
Sh. E.
, “
Initial Heat Flux Densities and Duration of Non-Stationary Nucleate Boiling During Quenching
,”
5th WSEAS Int. Conf. on Heat and Mass Transfer (HMT’08)
,
Acapulco, Mexico
, 25–27 January
2008
, pp.
104
109
.
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