Abstract

HOTPITS is a set of physics-based modeling tools for treating Type II hot corrosion in Ni-based superalloys. The methodology includes modeling the nucleation, growth, and coalescence of pits and microcracks as a random process, as well as the transition of pits to micrcracks and the propagation of the resulting large crack to failure. In this investigation, critical experiments were performed on coupon and low-cycle fatigue (LCF) specimens in order to validate the hot corrosion and the fatigue models in HOTPITS. The pit nucleation, growth, and coalescence models in HOTPITS including the assumption of a random process are validated by the hot corrosion critical experiments performed at two salt contents. The LCF critical experiments, performed using a marker band protocol, validated the stress concentration factor-based models used to predict the pit-to-crack transition in the HOTPITS tool.

References

1.
Goebel
,
J. A.
,
Pettit
,
F. S.
, and
Goward
,
G. W.
,
1973
, “
Mechanisms for the Hot Corrosion of Nickel-Based Alloys
,”
Metall. Trans.
,
4
(
1
), pp.
261
278
. 10.1007/BF02649626
2.
Chiang
,
K. T.
,
Pettit
,
F. S.
, and
Meier
,
G. H.
,
1983
,
High Temperature Corrosion
,
R. A.
Rapp
, ed.,
National Association of Corrosion Engineers
,
Houston, TX
, pp.
519
530
.
3.
Pettit
,
F. S.
, and
Meier
,
G. H.
,
1984
, “Oxidation and Hot Corrosion of Superalloys,”
Superalloys 84
,
Gell
,
M.
,
Kortovich
,
C. S.
,
Bricknell
,
R. H.
,
Kent
,
W. B.
and
Radavich
,
J. F.
, eds.,
TMS
,
Warrendale, PA
, pp.
651
687
.
4.
Rapp
,
R.
,
2002
, “
Hot Corrosion of Materials; a Fluxing Mechanism?
,”
Corros. Sci.
,
44
(
2
), pp.
209
221
. 10.1016/S0010-938X(01)00057-9
5.
Groh
,
J. R.
, and
Duvelius
,
R. W.
,
2001
, “Influence of Corrosion Pitting on Alloy 718 Fatigue Capability,”
Superalloys 718, 625, 706 and Various Derivatives
,
L. A.
Loria
, ed.,
TMS
,
Warrendale, PA
, pp.
583
592
.
6.
Gabb
,
T. P.
,
Telesman
,
J.
,
Kantzos
,
P. T.
,
Smith
,
J. W.
, and
Browning
,
P. F.
,
2004
, “Effects of High Temperature Exposures on Fatigue Life of Disk Superalloys,”
Superalloys 2004
,
K. A.
Green
,
T. M.
Pollock
,
H.
Harada
,
T. E.
Howson
,
R. C.
Reed
,
J. J.
Schirra
, and
S.
Watson
, eds.,
TMS
,
Warrendale, PA
, pp.
269
274
.
7.
Gabb
,
T. P.
,
Telesman
,
J.
,
Hazel
,
B.
, and
Mourer
,
D. P.
,
2010
, “
The Effects of Hot Corrosion Pits on the Fatigue Resistance of a Disk Superalloy
,”
J. Mater. Eng. Perform.
,
19
(
1
), pp.
77
89
. 10.1007/s11665-009-9399-5
8.
Birbilis
,
N.
, and
Buchheit
,
R. G.
,
2008
, “
Measurement and Discussion of Low-Temperature Hot Corrosion Damage Accumulation Upon Nickel-Based Superalloy René 104
,”
Metall. Mater. Trans. A
,
39
(
13
), pp.
3224
3232
. 10.1007/s11661-008-9662-7
9.
Luthra
,
K. L.
, and
Shores
,
D. A.
,
1980
, “
Mechanism of Na2SO4 Induced Corrosion at 600°–900°C
,”
J. Electrochem. Soc.
,
127
(
10
), pp.
2202
2210
. 10.1149/1.2129375
10.
Gokoglu
,
S. A.
, and
Santorp
,
G. J.
,
1987
,
High Temperature Alloys for Gas Turbines and Other Applications
,
W.
Betz
,
R.
Brunetaud
,
D.
Coutsouradis
,
H.
Fischmeister
,
T. B.
Gibbons
,
I.
Kvernes
,
Y.
Lindblom
,
J. B.
Marriott
, and
D. B.
Meadowcroft
, eds.,
Reidel Publishing Co.
,
Dordrecht, Germany
, pp.
1117
1126
.
11.
Leyens
,
C.
,
Wright
,
I. G.
, and
Pint
,
B. A.
,
1999
, “Hot Corrosion of Nickel-Based Alloys in Biomass-Derived Fuel Simulated Atmosphere,”
Elevated Temperature Coatings: Science and Technology III
, ed.
J. M.
Hampikian
and
N. B.
Dahotre
, eds.,
TMS
,
Warrendale, PA
, pp.
79
90
.
12.
Encinas-Oropesa
,
A.
,
Drew
,
G. L.
,
Hardy
,
M. C.
,
Leggett
,
A. J.
,
Nicholls
,
J. R.
, and
Simms
,
N. J.
, “Effects of Oxidation and Hot Corrosion in a Nickel Disc Alloy,” in
Superalloy 2008
,
R. C.
Reed
,
K. A.
Green
,
P.
Caron
,
T. P.
Gabb
,
M. G.
Fahrmann
,
E. S.
Huron
, and
S. A.
Woodard
, eds.,
TMS
,
Warrendale, PA
,
2008
, pp.
609
618
.
13.
Goodrum
,
W.
,
Chan
,
K. S.
,
Enright
,
M. P.
,
Burns
,
J. T.
, and
Mills
,
D. M.
,
2018
, “Development of Physics-based Modeling Tools for Life-prediction and Durability Assessment of Advance Materials,” Phase II Final Report, NNX15CC33C,
ERI
,
Charlottesville, VA
.
14.
Southwest Research Institute
,
2013
, “
DARWIN® User’s Guide
”,
San Antonio, TX
.
15.
Chan
,
K. S.
,
Enright
,
M. P.
,
Moody
,
J. P.
and
Fitch
,
S. H. K.
,
2016
, “Physics-based Modeling Tools for Predicting Type II Hot Corrosion in Ni-Based Superalloys,”
Superalloy 2016
,
M.
Hardy
,
E.
Huron
,
U.
Glatzel
,
B.
Griffin
,
B.
Lewis
,
C.
Rae
,
V.
Seetharaman
, and
S.
Tin
, eds.,
Wiley
,
Hoboken, NJ
, pp.
917
925
.
16.
Chan
,
K. S.
,
Enright
,
M. P.
,
Moody
,
J.
,
Thomas
,
C.
, and
Goodrum
,
W.
,
2019
, “
HOTPITS: The DARWIN Approach to Assessing Risk of Hot Corrosion-Induced Fracture in Gas Turbine Components
,”
Eng. Fracture Mechanics
,
(Under Review)
.
17.
Gabb
,
T. P.
,
Garg
,
A.
,
Ellis
,
D. L.
, and
O’Connor
,
K. M.
,
2004
, “Detailed Microstructural Characterization of the Disk Alloy ME3,” NASA/TM-2004-213066,
NASA Glenn Research Center
,
Cleveland, OH
.
18.
Telesman
,
J.
,
Gabb
,
T. P.
,
Yamada
,
Y.
, and
Draper
,
S. L.
,
2016
, “
Fatigue Resistance of a Hot Corrosion Exposed Disk Superalloy at Varied Test Temperatures
,”
Mater. High Temp.
,
33
(
4–5
), pp.
517
527
. 10.1080/09603409.2016.1179000
19.
Draper
,
S. L.
,
2015
, Private communication,
NASA Glenn Research Center
,
Cleveland, OH
.
20.
Donahue
,
J. R.
, and
Burns
,
J. T.
,
2016
, “
Effect of Chloride Concentration on the Corrosion-Fatigue Crack Behavior of an Age-Hardenable Martensitic Stainless Steel
,”
Int. J Fatigue
,
91
, pp.
79
99
. 10.1016/j.ijfatigue.2016.05.022
21.
Burns
,
J. T.
,
Larsen
,
J. M.
, and
Gangloff
,
R. P.
,
2011
, “
Driving Forces for Localized Corrosion to Fatigue Crack Transition in Al-Zn-Mg-Cu
,”
Fatigue Fract. Eng. Mater. Struct.
,
34
(
10
), pp.
745
773
. 10.1111/j.1460-2695.2011.01568.x
22.
Jamieson
,
A.
,
2018
, “
Hot Corrosion Effects on the Fatigue Behavior of a Nickel-Based Superalloy ME3 (Rene 104)
,”
MS thesis
,
University of Virginia
,
Charlottesville, VA
.
23.
Kitagawa
,
H.
, and
Takahashi
,
S.
,
1976
, “
Applicability of Fracture Mechanics to Very Small Cracks or the Cracks in the Early Stages
,”
Proceedings of the Second International Conference on Mechanical Behavior of Materials, American Society for Metals
,
Metals Park, OH
,
Aug. 16–20
, pp.
627
631
.
24.
Gabb
,
T. P.
,
Telesman
,
J.
,
Kantzos
,
P. T.
, and
O’Connor
,
K.
,
2002
, Characterization of the Temperature Capabilities of Advanced Disk Alloy ME3,”
NASA/TM-2002-211796
, (
NASA Glenn Research Center
,
Cleveland, OH
.
25.
Lindley
,
T. C.
,
McIntyre
,
P.
, and
Trant
,
P. J.
,
1982
, “
Fatigue Crack Initiation at Corrosion Pits
,”
Metals Technology
,
9
(
1
), pp.
135
142
. 10.1179/030716982803286403
You do not currently have access to this content.